It's not possible to unlink your Skype and Microsoft accounts. When you link your Skype and Microsoft accounts, everything is merged together, allowing you to sign in to all your Microsoft services - including Skype, Office Online, Outlook, OneNote, OneDrive, Xbox, and more - with just one password.
Did you accidentally merge your Skype account with the wrong Microsoft account? In some cases it may be possible to move it to a different Microsoft account.
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