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With the latest version of Skype for Windows desktop and Microsoft Outlook 2010 or higher*, you have yet another easy way to keep in touch with your Skype contacts. If you have your contact’s Skype primary email address in your Microsoft Outlook Address Book, or if they send an email to your Microsoft Outlook account from their Skype primary email address, you can see their status, send them instant messages and call them directly from Microsoft Outlook.
*The preview version of Microsoft Outlook 2013 doesn‘t support linking Skype contact list to Outlook Address Book. Visit Microsoft Store for product information.
Learn more about adding contacts on Skype.
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No emergency calls with Skype Skype is not a replacement for your telephone and can't be used for emergency calling