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You may want to run multiple Skype accounts at the same time if there's one you use just for work, and another one for friends and family. While it’s not possible to run more than one instance of Skype on the same device at the same time, there are still a few ways you can access more than one account at a time:
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No emergency calls with Skype Skype is not a replacement for your telephone and can't be used for emergency calling